Haloalkanes and Haloarenes

Match the major products obtained in the reactions given in List-I with the corresponding structures in List-II and choose the correct option.

The volume of 1 M aqueous $\ce{H2SO4}$ required to completely neutralize the ammonia evolved from 5.72 g of L in Kjeldahl's method of nitrogen estimation is ____ mL.

In sulphur estimation by Carius method, the amount of $\ce{BaSO4}$ formed from 3.79 g of M is ____ g.

Given below are two statements :

Statement (I) : Benzyl chloride reacts faster in $\mathrm S_\mathrm N1$ mechanism than ethyl chloride.

Statement (II) : Ethyl carbocation intermediate is less stabilized by hyperconjugation than benzyl carbocation by resonance.

In the light of the above statements, choose the correct answer from the options given below :

Correct statements regarding alkyl halides (R-X) among the following are :

A. Alcohol being less polar solvent as compared to water, alcoholic KOH favours elimination reaction with R-X.

B. Order of reactivity towards $\mathrm S_\mathrm N1$ mechanism is $\ce{C6H5-CH2-Cl} > \ce{C6H5-CHCl-C6H5}$.

C. Non substituted aryl halides exhibit properties similar to alkyl halides.

D. Vinyl chloride is an example of haloalkene and allyl chloride is an example of haloalkyne.

E. R-Cl can be prepared by reacting R-OH with $\ce{SOCl2}$ but Ar-Cl cannot be prepared by reacting Ar-OH with $\ce{SOCl2}$.

Choose the correct answer from the options given below :

Match the LIST-I with LIST-II

Choose the correct answer from the options given below:

RMgI when treated with ice cold water liberated a gas which occupied 1.4 dm³/g at STP. The gas produced is further reacted with iodine in presence of $\ce{HIO3}$ to give compound (X). Compound (X) in presence of Na and dry ether produced compound (Y). Molar mass of compound (Y) is ________ g mol$^{-1}$. (Nearest integer)

An optically active alkyl bromide $\ce{C4H9Br}$, reacts with ethanolic KOH to form major compound [A] which reacts with bromine to give compound [B]. Compound [B] reacts with ethanolic KOH and sodamide to give compound [C]. One molecule of water adds to compound [C] on warming with mercuric sulphate and dilute sulphuric acid at 333 K to form compound [D]. The functional group in compound D will be confirmed by :

Given below are two statements :

Statement I : Due to increase in van der Waals forces, the order of boiling points is $\ce{CH3CH2CH2I}>\ce{CH3CH2I}>\ce{CH3I}$.

Statement II : As 1,4-dichlorobenzene is more symmetric, its melting point is higher than 1,2-dichlorobenzene, however its boiling point is lower than 1,2-dichlorobenzene.

In the light of the above statements, choose the correct answer from the options given below :

For the reaction sequence given below, the correct statement(s) is(are)

$$\text{cyclohexene} \xrightarrow{\ce{HBr}} \mathbf{P},\qquad \mathbf{P} \xrightarrow{\text{Finkelstein reaction}} \mathbf{Q},\qquad \mathbf{P} \xrightarrow{\text{Swarts reaction}} \mathbf{R}$$

(In the options, X is any atom other than carbon and hydrogen, and it is different in P, Q and R)

The reaction sequence given below is carried out with 16 moles of X. The yield of the major product in each step is given below the product in parentheses. The amount (in grams) of S produced is _____.

Use: Atomic mass (in amu): H = 1, C = 12, O = 16, Br = 80

The correct reaction/reaction sequence that would produce a dicarboxylic acid as the major product is

Reaction of iso-propylbenzene with $\ce{O2}$ followed by the treatment with $\ce{H3O+}$ forms phenol and a by-product P. Reaction of P with 3 equivalents of $\ce{Cl2}$ gives compound Q. Treatment of Q with $\ce{Ca(OH)2}$ produces compound R and calcium salt S.

The correct statement(s) regarding P, Q, R and S is(are)

In the following reaction sequence, the major product Q is

$$\text{L-Glucose} \xrightarrow[\text{ii) } \ce{Cr2O3},\ 775\,\mathrm{K},\ 10\text{-}20\,\mathrm{atm}]{\text{i) HI},\ \Delta} \mathbf{P} \xrightarrow[\text{UV}]{\ce{Cl2}\ \text{(excess)}} \mathbf{Q}$$

Match the reactions in List-I with the features of their products in List-II and choose the correct option.

In the following reactions, P, Q, R, and S are the major products.

The correct statement about P, Q, R, and S is

The weight percentage of hydrogen in Q, formed in the following reaction sequence, is _____.

[Given: Atomic mass of H = 1, C = 12, N = 14, O = 16, S = 32, Cl = 35]

The number of isomeric tetraenes (NOT containing $sp$-hybridized carbon atoms) that can be formed from the following reaction sequence is ________.

In the given reaction sequence, the major product 'C' is :
$$\mathrm{C_8H_{10}\xrightarrow[H_2SO_4]{HNO_3}A\xrightarrow[\Delta]{Br_2}B\xrightarrow[KOH]{alcoholic}C}$$

$$\text{(structure)}\xrightarrow[\mathrm{H_2O}]{\mathrm{NaOH}}\underset{\text{(Major Product)}}{\mathrm P}$$
Consider the above reaction. The number of $\pi$ electrons present in the product 'P' is ______.