Main 18 · Advanced 36
Optical isomerism and chirality
- Main 2022ChemistrySingle correct
Given below are two statements.
Statement I: The compound (A) shown, a carbon bearing NO, H, a (Z)-prop-1-enyl group and an (E)-prop-1-enyl group, is optically active.
Statement II: The second compound shown is mirror image of above compound A.
In the light of the above statement, choose the most appropriate answer from the options given below.
- Main 2022ChemistryInteger
The number of stereoisomers formed in a reaction of (±)Ph(C=O)C(OH)(CN)Ph with HCN is _______.
[where Ph is −CH]
- Advanced 2021ChemistrySingle correct
Among the following, the conformation that corresponds to the most stable conformation of meso-butane-2,3-diol is
- Advanced 2021ChemistryMultiple correct
Given:
,
The compound(s), which on reaction with will give the product having degree of rotation, is(are)
- Advanced 2021ChemistryInteger
The maximum number of possible isomers (including stereoisomers) which may be formed on mono-bromination of 1-methylcyclohex-1-ene using and UV light is ____.
- Advanced 2020ChemistryList match
The Fischer projection of D-erythrose is shown below.
D-Erythrose and its isomers are listed as P, Q, R, and S in Column-I. Choose the correct relationship of P, Q, R, and S with D-erythrose from Column II.
- Advanced 2020ChemistryInteger
An organic compound () rotates plane-polarized light. It produces pink color with neutral solution. What is the total number of all the possible isomers for this compound?
- Advanced 2020ChemistryMultiple correct
Consider the following transformations of a compound P.
Choose the correct option(s).
- Advanced 2019ChemistryNumerical
Total number of isomers, considering both structural and stereoisomers, of cyclic ethers with the molecular formula is ______
- Advanced 2018ChemistryMultiple correct
In the following reaction sequence, the correct structure(s) of X is (are)
- Advanced 2018ChemistryMultiple correct
The Fischer presentation of D-glucose is given below.
The correct structure(s) of β-L-glucopyranose is (are)
- Advanced 2018ChemistryNumerical
For the given compound X, the total number of optically active stereoisomers is ____.
- Advanced 2017ChemistryMultiple correct
The correct statement(s) for the following addition reactions is(are)
(i) trans-2-butene M and N
(ii) cis-2-butene O and P
- Main 2017ChemistrySingle correct
3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product. The number of possible stereoisomers for the product is :
- Advanced 2016ChemistryInteger
In the following monobromination reaction, the number of possible chiral products is
(Enantiomerically pure 2-bromopentane, 1.0 mole, shown as a Fischer projection)
- Main 2016ChemistrySingle correct
The absolute configuration of the compound shown is :
- Advanced 2015ChemistryInteger
The total number of stereoisomers that can exist for M is
- Advanced 2015ChemistryMultiple correct
Compound(s) that on hydrogenation produce(s) optically inactive compound(s) is(are)
- Advanced 2015ChemistryMultiple correct
The structure of D-(+)-glucose is shown (Fischer projection: CHO at top; OH on the right, left, right and right at C2, C3, C4 and C5; CH₂OH at the bottom).
The structure of L-(−)-glucose is
- Main 2015ChemistrySingle correct
The optically inactive compound from the following is :