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← JEE Main 2017 · 2 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 58 of 90

JEE Main 2017 · 2 Apr · Shift 1, Chemistry question 58

3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product. The number of possible stereoisomers for the product is :

Choose one option
Answer and worked solution

Official answer: B

Anti-Markovnikov addition (peroxide effect) puts Br on C2: CHX3−CHBr−CH(CHX3)−CHX2CHX3\ce{CH3-CHBr-CH(CH3)-CH2CH3}. C2 and C3 are both stereocentres, giving 22=42^2=4 stereoisomers.