SN1 and SN2

The volume of 1 M aqueous $\ce{H2SO4}$ required to completely neutralize the ammonia evolved from 5.72 g of L in Kjeldahl's method of nitrogen estimation is ____ mL.

In sulphur estimation by Carius method, the amount of $\ce{BaSO4}$ formed from 3.79 g of M is ____ g.

Given below are two statements :

Statement (I) : Benzyl chloride reacts faster in $\mathrm S_\mathrm N1$ mechanism than ethyl chloride.

Statement (II) : Ethyl carbocation intermediate is less stabilized by hyperconjugation than benzyl carbocation by resonance.

In the light of the above statements, choose the correct answer from the options given below :

Correct statements regarding alkyl halides (R-X) among the following are :

A. Alcohol being less polar solvent as compared to water, alcoholic KOH favours elimination reaction with R-X.

B. Order of reactivity towards $\mathrm S_\mathrm N1$ mechanism is $\ce{C6H5-CH2-Cl} > \ce{C6H5-CHCl-C6H5}$.

C. Non substituted aryl halides exhibit properties similar to alkyl halides.

D. Vinyl chloride is an example of haloalkene and allyl chloride is an example of haloalkyne.

E. R-Cl can be prepared by reacting R-OH with $\ce{SOCl2}$ but Ar-Cl cannot be prepared by reacting Ar-OH with $\ce{SOCl2}$.

Choose the correct answer from the options given below :

Match the LIST-I with LIST-II

Choose the correct answer from the options given below:

RMgI when treated with ice cold water liberated a gas which occupied 1.4 dm³/g at STP. The gas produced is further reacted with iodine in presence of $\ce{HIO3}$ to give compound (X). Compound (X) in presence of Na and dry ether produced compound (Y). Molar mass of compound (Y) is ________ g mol$^{-1}$. (Nearest integer)

For the reaction sequence given below, the correct statement(s) is(are)

$$\text{cyclohexene} \xrightarrow{\ce{HBr}} \mathbf{P},\qquad \mathbf{P} \xrightarrow{\text{Finkelstein reaction}} \mathbf{Q},\qquad \mathbf{P} \xrightarrow{\text{Swarts reaction}} \mathbf{R}$$

(In the options, X is any atom other than carbon and hydrogen, and it is different in P, Q and R)

Match the reactions in List-I with the features of their products in List-II and choose the correct option.

In the following reactions, P, Q, R, and S are the major products.

The correct statement about P, Q, R, and S is

$$\text{(structure)}\xrightarrow[\mathrm{H_2O}]{\mathrm{NaOH}}\underset{\text{(Major Product)}}{\mathrm P}$$
Consider the above reaction. The number of $\pi$ electrons present in the product 'P' is ______.

The correct order of nucleophilicity is

The major product of the following reaction is :

Which one of the following compounds is inactive towards S$_N$1 reaction ?

Most stable product of the following reaction is :

In the above reaction product B is:

Product B is

The structure of A in the given reaction is :

Ethyl chloride is treated with AgCN in $\mathrm{C_2H_5OH-H_2O}$ to give 'A' (Major Product), and with NaCN in $\mathrm{C_2H_5OH-H_2O}$ to give 'B' (Major Product), as shown.

Considering the above reactions, the compound 'A' and compound 'B' respectively are :

Compound 'A' undergoes following sequence of reactions to give compound 'B'. The correct structure and chirality of compound 'B' is

[where Et is −C$_2$H$_5$]

Compound 'A' (2-bromo-3-methylbutane) is treated with (i) Mg, Et$_2$O (ii) D$_2$O to give B.

The reaction of $\mathbf Q$ with PhSNa yields an organic compound (major product) that gives positive Carius test on treatment with $\ce{Na2O2}$ followed by addition of $\ce{BaCl2}$. The correct option(s) for $\mathbf Q$ is(are)

Which of the following plots is(are) correct for the given reaction?

($[\mathbf P]_0$ is the initial concentration of P)