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← JEE Main 2026 · 8 Apr · Shift 2
ChemistryInteger+4 / -1Question 72 of 75

JEE Main 2026 · 8 Apr · Shift 2, Chemistry question 72

'xx' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. 'yy' is the major product obtained from the benzene by reacting it with ethanoyl chloride in the presence of anhydrous AlClX3\ce{AlCl3}. Product (major) obtained by heating xx and yy in the presence of alkali is zz. Total number of π\pi (pi) electrons in zz is ________.

Answer and worked solution

Official answer: 16

x and y.

  • x: Gattermann-Koch formylation gives benzaldehyde.
  • y: Friedel-Crafts acylation gives acetophenone.

z. Claisen-Schmidt condensation gives chalcone, PhCH=CH−CO−Ph\ce{PhCH=CH-CO-Ph}.

π electrons. Two rings (12), C=C (2) and C=O (2): 16.

Answer: 16