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← JEE Main 2022 · 30 Jul · Shift 2
ChemistryInteger+4 / -1Question 54 of 90

JEE Main 2022 · 30 Jul · Shift 2, Chemistry question 54

50 mL of 0.1 M CH3_3COOH is titrated against 0.1 M NaOH solution. When 10 mL of NaOH is added, the pH of the solution becomes _______ ×10−1\times10^{-1}. (nearest integer)

Given: pKa (CH3_3COOH) = 4.8, log 2 = 0.3

Answer and worked solution

Official answer: 42

Buffer. 1 mmol of acetate and 4 mmol of acid remain: pH =4.8+log⁡14=4.8−0.6=4.2=42×10−1=4.8+\log\frac14=4.8-0.6=4.2=42\times10^{-1}.

Answer: 42