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← JEE Main 2022 · 30 Jul · Shift 2
ChemistryInteger+4 / -1Question 53 of 90

JEE Main 2022 · 30 Jul · Shift 2, Chemistry question 53

31 g of ethylene glycol is mixed with 500 g of water. The freezing point of the aqueous solution is _______ K. (in nearest integer)

(Kf_f of water = 1.86 K kg mol−1^{-1})

[Molar mass of C, H, O are 12, 1, 16 g mol−1^{-1}]

Answer and worked solution

Official answer: 271

Molality 31/620.5=1\frac{31/62}{0.5}=1 m: ΔTf=1.86\Delta T_f=1.86 K, so the freezing point is 273.15−1.86≈271273.15-1.86\approx271 K.

Answer: 271