Main 17 · Advanced 11
Integrated rate equations
- Advanced 2018ChemistryMultiple correct
For a first order reaction at constant volume and 300 K, the total pressure at the beginning () and at time are and , respectively. Initially, only A is present with concentration , and is the time required for the partial pressure of A to reach 1/3 of its initial value. The correct option(s) is (are)
(Assume that all these gases behave as ideal gases)
- Main 2016ChemistrySingle correct
Decomposition of follows a first order reaction. In fifty minutes the concentration of decreases from 0.5 to 0.125 M in one such decomposition. When the concentration of reaches 0.05 M, the rate of formation of will be :
- Main 2015ChemistrySingle correct
The reaction
follows first order kinetics. The pressure of a vessel containing only was found to increase from 50 mm Hg to 87.5 mm Hg in 30 min. The pressure exerted by the gases after 60 min. will be (Assume temperature remains constant) : - Main 2014ChemistrySingle correct
The half-life period of a first order reaction is 15 minutes. The amount of substance left after one hour will be :
- Advanced 2013ChemistrySingle correct
In the reaction,
the time taken for 75% reaction of P is twice the time taken for 50% reaction of P. The concentration of Q varies with reaction time as shown in the figure. The overall order of the reaction is - Advanced 2012ChemistryInteger
An organic compound undergoes first-order decomposition. The time taken for its decomposition to 1/8 and 1/10 of its initial concentration are and respectively. What is the value of ? (take )
- Advanced 2011ChemistryMultiple correct
For the first order reaction
- Advanced 2010ChemistryInteger
The concentration of R in the reaction R P was measured as a function of time and the following data is obtained:
[R] (molar) 1.0 0.75 0.40 0.10 t (min.) 0.0 0.05 0.12 0.18 The order of the reaction is