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← JEE Main 2026 · 6 Apr · Shift 2
ChemistryInteger+4 / -1Question 72 of 75

JEE Main 2026 · 6 Apr · Shift 2, Chemistry question 72

An alkane (Y) requires 8 moles of oxygen for complete combustion and on chlorination with ClX2/hν\ce{Cl2}/h\nu, (Y) gives only one monochlorinated product (Z). The total number of primary carbon atoms in (Y) is ________.

Answer and worked solution

Official answer: 4

Alkane. CXnHX2n+2\ce{C_nH_{2n+2}} needs 3n+12\dfrac{3n+1}2 mol of OX2\ce{O2}. Setting this to 8 gives n=5n=5.

One monochloro product. All hydrogens must be equivalent: neopentane, C(CHX3)X4\ce{C(CH3)4}.

Primary carbons: 4.

Answer: 4