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← JEE Main 2026 · 4 Apr · Shift 1
ChemistryInteger+4 / -1Question 74 of 75

JEE Main 2026 · 4 Apr · Shift 1, Chemistry question 74

The pH of a solution obtained by mixing 5 mL of 0.1 M NHX4OH\ce{NH4OH} solution with 250 mL of 0.1 M NHX4Cl\ce{NH4Cl} solution is ________ ×10−2\times10^{-2}. (Nearest integer)
Given: pKb(NHX4OH)=4.74pK_b(\ce{NH4OH})=4.74, log⁡2=0.30\log2=0.30, log⁡3=0.48\log3=0.48, log⁡5=0.70\log5=0.70

Answer and worked solution

Official answer: 756

Basic buffer. NHX4OH\ce{NH4OH} 0.5 mmol and NHX4Cl\ce{NH4Cl} 25 mmol:
pOH=4.74+log⁡250.5=4.74+1.70=6.44.\text{pOH}=4.74+\log\frac{25}{0.5}=4.74+1.70=6.44.

pH =7.56=756×10−2=7.56=756\times10^{-2}.

Answer: 756