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← JEE Main 2022 · 30 Jun · Shift 1
ChemistryInteger+4 / -1Question 86 of 90

JEE Main 2022 · 30 Jun · Shift 1, Chemistry question 86

In the following brown complex, the oxidation state of iron is +______.

[Fe(H2O)6]2++NO→[Fe(H2O)5(NO)]2+Brown complex+H2O\mathrm{[Fe(H_2O)_6]^{2+}+NO\rightarrow\underset{Brown\ complex}{[Fe(H_2O)_5(NO)]^{2+}}+H_2O}

Answer and worked solution

Official answer: 2

Keyed reading. Counting NO as a neutral ligand, iron keeps its +2 state from [Fe(H2O)6]2+\mathrm{[Fe(H_2O)_6]^{2+}}.

Note. The usual modern description has NO bound as NO+\mathrm{NO^+}, which would make iron +1; the key takes +2.

Answer: 2