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← JEE Main 2022 · 27 Jun · Shift 2
ChemistryInteger+4 / -1Question 81 of 90

JEE Main 2022 · 27 Jun · Shift 2, Chemistry question 81

116 g of a substance upon dissociation reaction, yields 7.5 g of hydrogen, 60 g of oxygen and 48.5 g of carbon. Given that the atomic masses of H, O and C are 1, 16 and 12, respectively. The data agrees with how many formulae of the following ? ______.

A. CH3COOH\mathrm{CH_3COOH} B. HCHO C. CH3OOCH3\mathrm{CH_3OOCH_3} D. CH3CHO\mathrm{CH_3CHO}

Answer and worked solution

Official answer: 2

Moles. H 7.5, O 3.75, C 4.04: close to C : H : O = 1 : 2 : 1, the empirical formula CH2O\mathrm{CH_2O}.

Matches. CH3COOH\mathrm{CH_3COOH} (C2H4O2\mathrm{C_2H_4O_2}) and HCHO. (CH3OOCH3\mathrm{CH_3OOCH_3} and CH3CHO\mathrm{CH_3CHO} do not fit.) So 2.

Answer: 2