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← JEE Main 2022 · 27 Jun · Shift 2
ChemistryList match+4 / -1Question 80 of 90

JEE Main 2022 · 27 Jun · Shift 2, Chemistry question 80

Match List I with List II.

Choose the correct answer from the options given below:

List I (Anion)

  • A
    CO32−\mathrm{CO_3^{2-}}
  • B
    S2−\mathrm{S^{2-}}
  • C
    SO32−\mathrm{SO_3^{2-}}
  • D
    NO2−\mathrm{NO_2^-}

List II (gas evolved on reaction with dil $\mathrm{H_2SO_4}$)

  • I
    Colourless gas which turns lead acetate paper black.
  • II
    Colourless gas which turns acidified potassium dichromate solution green.
  • III
    Brown fumes which turns acidified KI solution containing starch blue.
  • IV
    Colourless gas evolved with brisk effervescence, which turns lime water milky.
Choose one option
Answer and worked solution

Official answer: D

Gases with dilute acid. CO32−\mathrm{CO_3^{2-}}: CO2\mathrm{CO_2}, effervescence, milky lime water (IV). S2−\mathrm{S^{2-}}: H2S\mathrm{H_2S}, blackens lead acetate (I). SO32−\mathrm{SO_3^{2-}}: SO2\mathrm{SO_2}, turns dichromate green (II). NO2−\mathrm{NO_2^-}: brown NO2\mathrm{NO_2} fumes, starch-iodide blue (III).

(D)