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← JEE Main 2017 · 8 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 39 of 90

JEE Main 2017 · 8 Apr · Shift 1, Chemistry question 39

The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.

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Answer and worked solution

Official answer: B

For A, ln⁡2=EaR(1300−1310)=EaR⋅19300\ln2=\dfrac{E_a}R\left(\dfrac1{300}-\dfrac1{310}\right)=\dfrac{E_a}R\cdot\dfrac1{9300}. For B, with 2Ea2E_a:
1300−1T=118600  ⟹  T=1860061=304.92 K.\frac1{300}-\frac1T=\frac1{18600}\implies T=\frac{18600}{61}=304.92\text{ K}.
The increase is 4.92 K.