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← JEE Main 2014 · 11 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 40 of 90

JEE Main 2014 · 11 Apr · Shift 1, Chemistry question 40

Based on the equation :
ΔE=−2.0×10−18 J(1n22−1n12)\Delta E=-2.0\times10^{-18}\text{ J}\left(\frac1{n_2^2}-\frac1{n_1^2}\right)
the wavelength of the light that must be absorbed to excite hydrogen electron from level n=1n=1 to level n=2n=2 will be : (h=6.625×10−34h=6.625\times10^{-34} Js, C=3×108C=3\times10^8 ms−1^{-1})

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Answer and worked solution

Official answer: A

ΔE=2.0×10−18(1−14)=1.5×10−18\Delta E=2.0\times10^{-18}\left(1-\frac14\right)=1.5\times10^{-18} J, so
λ=hcΔE=6.625×10−34×3×1081.5×10−18=1.325×10−7 m.\lambda=\frac{hc}{\Delta E}=\frac{6.625\times10^{-34}\times3\times10^8}{1.5\times10^{-18}}=1.325\times10^{-7}\text{ m}.