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← JEE Main 2014 · 9 Apr · Shift 1
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JEE Main 2014 · 9 Apr · Shift 1, Physics question 27

If the binding energy of the electron in a hydrogen atom is 13.6 eV, the energy required to remove the electron from the first excited state of LiX++\ce{Li^{++}} is :

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Answer and worked solution

Official answer: B

En=−13.6Z2n2E_n=-13.6\dfrac{Z^2}{n^2} eV. For LiX2+\ce{Li^2+} (Z=3Z=3) in the first excited state (n=2n=2): E=−13.6×94=−30.6E=-13.6\times\frac94=-30.6 eV. Removing the electron needs 30.6 eV.