JEE Advanced 2022 · Paper 1, Chemistry question 15

LIST-I

• I
  $\text{rate} = \dfrac{k[\mathrm X]}{\mathrm X_s + [\mathrm X]}$ under all possible initial concentrations of X
• II
  $\text{rate} = \dfrac{k[\mathrm X]}{\mathrm X_s + [\mathrm X]}$ where initial concentrations of X are much less than $\mathrm X_s$
• III
  $\text{rate} = \dfrac{k[\mathrm X]}{\mathrm X_s + [\mathrm X]}$ where initial concentrations of X are much higher than $\mathrm X_s$
• IV
  $\text{rate} = \dfrac{k[\mathrm X]^2}{\mathrm X_s + [\mathrm X]}$ where initial concentration of X is much higher than $\mathrm X_s$

LIST-II

• P
  Plot of half-life against initial concentration: straight line with positive slope and intercept (figure).

  
• Q
  Plot of half-life against initial concentration: horizontal line (figure).

  
• R
  Plot of rate against initial concentration: rises and levels off (figure).

  
• S
  Plot of [X] against time: straight falling line (figure).

  
• T
  Plot of ln[X] against time: straight falling line (figure).