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← JEE Advanced 2020 · Paper 2
ChemistryInteger+3 / -1Question 20 of 54

JEE Advanced 2020 · Paper 2, Chemistry question 2

Consider the following compounds in the liquid form:

OX2\ce{O2}, HF\ce{HF}, HX2O\ce{H2O}, NHX3\ce{NH3}, HX2OX2\ce{H2O2}, CClX4\ce{CCl4}, CHClX3\ce{CHCl3}, CX6HX6\ce{C6H6}, CX6HX5Cl\ce{C6H5Cl}.

When a charged comb is brought near their flowing stream, how many of them show deflection as per the following figure?

A liquid flows as a thin stream from a burette; a charged comb held to one side pulls the stream towards it, so the falling drops bend towards the comb.
Answer and worked solution

Official answer: 6

A stream is pulled towards a charged comb only if its molecules have a permanent dipole moment.

Polar (deflected): HF\ce{HF}, HX2O\ce{H2O}, NHX3\ce{NH3}, HX2OX2\ce{H2O2}, CHClX3\ce{CHCl3}, CX6HX5Cl\ce{C6H5Cl}.

Non-polar (not deflected): OX2\ce{O2}, CClX4\ce{CCl4} (tetrahedral), CX6HX6\ce{C6H6} (symmetric).

Answer: 6