As shown schematically in the figure, two vessels contain water solutions (at temperature ) of potassium permanganate () of different concentrations and molecules per unit volume with . When they are connected by a tube of small length and cross-sectional area , starts to diffuse from the left to the right vessel through the tube. Consider the collection of molecules to behave as dilute ideal gases and the difference in their partial pressure in the two vessels causing the diffusion. The speed of the molecules is limited by the viscous force on each molecule, where is a constant. Neglecting all terms of the order , which of the following is/are correct? ( is the Boltzmann constant)
← JEE Advanced 2020 · Paper 1
PhysicsMultiple correct+4 / -2Question 12 of 54
JEE Advanced 2020 · Paper 1, Physics question 12

Answer and worked solution
Official answer: A, B, C
Treat the dissolved molecules as an ideal gas, .
(A) Driving force. The partial-pressure difference across the tube acts on its cross-section:
(A) is true.
(B) Force balance. The tube holds about molecules, each moving at steady speed against the drag :
(B) is true.
(C) Rate.
(C) is true.
(D) As molecules move across, falls, so the rate falls too. (D) is false.
(A), (B), (C)