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JEE Advanced 2019 · Paper 2, Physics question 18

Passage

Answer Q.17 and Q.18 by appropriately matching the lists based on the information given in the paragraph

In a thermodynamic process on an ideal monatomic gas, the infinitesimal heat absorbed by the gas is given by TΔXT\Delta X, where TT is temperature of the system and ΔX\Delta X is the infinitesimal change in a thermodynamic quantity XX of the system. For a mole of monatomic ideal gas X=32Rln⁡(TTA)+Rln⁡(VVA)X = \frac32R\ln\left(\frac T{T_A}\right) + R\ln\left(\frac V{V_A}\right). Here, RR is gas constant, VV is volume of gas, TAT_A and VAV_A are constants.

The List-I below gives some quantities involved in a process and List-II gives some possible values of these quantities.

If the process on one mole of monatomic ideal gas is as shown in the TVTV-diagram with P0V0=13RT0P_0V_0 = \frac13RT_0, the correct match is,

T-V diagram: 1 (V₀, T₀/3) → 2 (2V₀, T₀/3) at constant temperature, then 2 → 3 (2V₀, T₀) at constant volume.

List-I

  • I
    Work done by the system in process 1→2→31\to2\to3
  • II
    Change in internal energy in process 1→2→31\to2\to3
  • III
    Heat absorbed by the system in process 1→2→31\to2\to3
  • IV
    Heat absorbed by the system in process 1→21\to2

List-II

  • P
    13RT0ln⁡2\frac13RT_0\ln2
  • Q
    13RT0\frac13RT_0
  • R
    RT0RT_0
  • S
    43RT0\frac43RT_0
  • T
    13RT0(3+ln⁡2)\frac13RT_0(3 + \ln2)
  • U
    56RT0\frac56RT_0
Choose one option
Answer and worked solution

Official answer: C

The process. 1→21\to2 is isothermal at T03\frac{T_0}3 from V0V_0 to 2V02V_0; 2→32\to3 is isochoric, heating the gas to T0T_0.

The quantities.

  • I. Work. Only the isothermal step does work: RT03ln⁡2R\frac{T_0}3\ln2, (P).
  • II. Change in internal energy. 32R⋅2T03=RT0\frac32R\cdot\frac{2T_0}3=RT_0, (R).
  • III. Heat over 1→2→31\to2\to3. 13RT0ln⁡2+RT0=13RT0(3+ln⁡2)\frac13RT_0\ln2+RT_0=\frac13RT_0(3+\ln2), (T).
  • IV. Heat in 1→21\to2. For an isothermal step it equals the work, 13RT0ln⁡2\frac13RT_0\ln2, (P).

(C)