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← JEE Advanced 2015 · Paper 1
PhysicsMultiple correct+4 / -2Question 16 of 60

JEE Advanced 2015 · Paper 1, Physics question 16

A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in equilibrium at temperature TT. Assuming the gases are ideal, the correct statement(s) is(are)

Choose one or more options
Answer and worked solution

Official answer: A, B, D

  • (A) Average energy per mole: 12(52RT+32RT)=2RT\frac12\left(\frac52RT+\frac32RT\right)=2RT. True.
  • (B) For the mixture, CV=2RC_V=2R, CP=3RC_P=3R, γ=32\gamma=\frac32 and M=3M=3 g/mol. For helium, γ=53\gamma=\frac53 and M=4M=4 g/mol. So
    vmix2vHe2=1.5/3(5/3)/4=65.\frac{v_{mix}^2}{v_{He}^2}=\frac{1.5/3}{(5/3)/4}=\frac65.
    True.
  • (C), (D) vrms∝M−1/2v_{rms}\propto M^{-1/2}, so vHevH2=24=12\dfrac{v_{He}}{v_{H_2}}=\sqrt{\dfrac24}=\dfrac1{\sqrt2}. (D) is true and (C) is false.

(A), (B), (D)