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← JEE Advanced 2013 · Paper 2
ChemistrySingle correct+3 / -1Question 34 of 60

JEE Advanced 2013 · Paper 2, Chemistry question 34

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Paragraph for Questions 33 and 34

An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl, gave a precipitate (P) and a filtrate (Q). The precipitate P was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with HX2S\ce{H2S} in a dilute mineral acid medium. However, it gave a precipitate (R) with HX2S\ce{H2S} in an ammoniacal medium. The precipitate R gave a coloured solution (S), when treated with HX2OX2\ce{H2O2} in an aqueous NaOH medium.

The coloured solution S contains

Choose one option
Answer and worked solution

Official answer: D

R. No precipitate with H₂S in acid (no group II ion), but a precipitate in ammoniacal medium: a group III/IV ion.

S. Hydrogen peroxide in NaOH oxidises Cr(OH)₃ to yellow chromate:
2 Cr(OH)X3+3 HX2OX2+4 NaOH→2 NaX2CrOX4+8 HX2O.\ce{2Cr(OH)3 + 3H2O2 + 4NaOH -> 2Na2CrO4 + 8H2O}.
(Fe, Cu or Zn would not give a coloured solution this way.)

(D)