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← JEE Main 2026 · 8 Apr · Shift 2
ChemistrySingle correct+4 / -1Question 64 of 75

JEE Main 2026 · 8 Apr · Shift 2, Chemistry question 64

The total number of aromatic compounds/species from the following is

Six species: p-benzoquinone; the tropylium cation; phenanthrene; 1,2-dihydronaphthalene; the cyclobutadienyl dication (one C=C and + on each of the other two carbons); a cyclohexadienyl anion (two C=C, a CH₂ and a carbanion).
Choose one option
Answer and worked solution

Official answer: C

Aromatic as keyed (cyclic, planar, fully conjugated, 4n+24n+2 π electrons):

  • Tropylium cation (6π).
  • Phenanthrene (14π).
  • Cyclobutenyl dication (2π, n=0n=0).

Not aromatic.

  • p-Benzoquinone: the ring is not a continuous aromatic π system.
  • The cyclohexadienyl anion: one ring carbon is sp³ (CHX2\ce{CH2}).
  • 1,2-Dihydronaphthalene: its CHX2CHX2\ce{CH2CH2} breaks conjugation in the second ring. The key does not count it, although it does contain a benzene ring.

Count: 3.

(C)