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← JEE Main 2026 · 6 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 63 of 75

JEE Main 2026 · 6 Apr · Shift 1, Chemistry question 63

RfR_f value for 2-methylpropene in a solvent system (Ethyl acetate + ether) is 0.42. 2-methylpropene is treated with dilute HX2SOX4\ce{H2SO4} to give major organic product (X). RfR_f value for (X) in the same solvent system under identical condition will be:

Choose one option
Answer and worked solution

Official answer: D

X. Acid-catalysed hydration of 2-methylpropene gives tert-butyl alcohol.

Rf. The alcohol is far more polar than the alkene. It is held more strongly by the polar stationary phase and moves less. So its RfR_f is lower: 0.12.

(D)