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← JEE Main 2026 · 5 Apr · Shift 2
ChemistrySingle correct+4 / -1Question 51 of 75

JEE Main 2026 · 5 Apr · Shift 2, Chemistry question 51

What volume of hydrogen gas at STP would be liberated by action of 50 mL of HX2SOX4\ce{H2SO4} of 50% purity (density = 1.3 g mL−1^{-1}) on 20 g of zinc ?

Given : Molar mass of H, O, S, Zn are 1, 16, 32, 65 g mol−1^{-1} respectively.

Choose one option
Answer and worked solution

Official answer: C

Moles of acid. 50×1.3×0.5=32.550\times1.3\times0.5=32.5 g of HX2SOX4\ce{H2SO4}, which is 32.598=0.332\tfrac{32.5}{98}=0.332 mol.

Moles of zinc. 2065=0.308\tfrac{20}{65}=0.308 mol.

Limiting reagent. Zn+HX2SOX4→ZnSOX4+HX2\ce{Zn + H2SO4 -> ZnSO4 + H2} is 1 : 1, so zinc limits.

Hydrogen. 0.3077×22.4≈6.8920.3077\times22.4\approx6.892 L.

(C)