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← JEE Main 2026 · 5 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 63 of 75

JEE Main 2026 · 5 Apr · Shift 1, Chemistry question 63

Given below are two statements:

Statement I: On the basis of inductive effect, the order of stability of alkyl carbanions is CHX3X−>CHX3−CHX2X−>(CHX3)X2CHX−>(CHX3)X3CX−\ce{CH3-}>\ce{CH3-CH2-}>\ce{(CH3)2CH-}>\ce{(CH3)3C-}.

Statement II: Allyl and benzyl carbanions are more stabilised by inductive effect and not by resonance effect.

In the light of the above statements, choose the correct answer from the options given below

Choose one option
Answer and worked solution

Official answer: C

Statement I. Alkyl groups are +I and destabilise a carbanion, so stability is CHX3X−>1∘>2∘>3∘\ce{CH3-}>1^\circ>2^\circ>3^\circ. Correct.

Statement II. Allyl and benzyl carbanions are stabilised by resonance, which delocalises the negative charge. Incorrect.

(C)