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JEE Main 2026 · 4 Apr · Shift 2, Chemistry question 62

Consider ∣x∣|x| is the difference in oxidation states of Mn in highest manganese fluoride and highest manganese oxide. The ions with ∣x∣|x| number of unpaired electrons from the following are:

A. ScX3+\ce{Sc^{3+}}

B. ZnX2+\ce{Zn^{2+}}

C. VX2+\ce{V^{2+}}

D. FeX2+\ce{Fe^{2+}}

E. CoX2+\ce{Co^{2+}}

Choose the correct answer from the options given below:

Choose one option
Answer and worked solution

Official answer: C

Find |x|. The highest fluoride is MnFX4\ce{MnF4} (+4) and the highest oxide MnX2OX7\ce{Mn2O7} (+7): ∣x∣=3|x|=3.

Ions with 3 unpaired electrons.

  • VX2+\ce{V^{2+}} (d3d^3) ✓ and CoX2+\ce{Co^{2+}} (d7d^7, high spin) ✓.
  • ScX3+\ce{Sc^{3+}} and ZnX2+\ce{Zn^{2+}} have 0; FeX2+\ce{Fe^{2+}} has 4.

C and E.

(C)