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← JEE Main 2022 · 30 Jul · Shift 2
ChemistrySingle correct+4 / -1Question 34 of 90

JEE Main 2022 · 30 Jul · Shift 2, Chemistry question 34

Freundlich's adsorption isotherm (in terms of concentration) is given by the expression; xm=K⋅C1/n\dfrac xm=K\cdot C^{1/n}. The possible conclusions that can be drawn from the expression are :

(A) When 1n=1\frac1n=1, the adsorption is directly proportional to concentration.

(B) When 1n=0\frac1n=0, the adsorption is independent of concentration.

(C) When n = 0, a plot of x/m vs C is a line parallel to x-axis

(D) When n = 0, a plot of x/m vs C is a curve.

Choose the correct option from the following :

Choose one option
Answer and worked solution

Official answer: D

Exponent. 1n=1\frac1n=1 gives xm=KC\frac xm=KC (A true); 1n=0\frac1n=0 gives xm=K\frac xm=K, independent of C (B true). The key also takes (C), reading the constant case as a line parallel to the C-axis; (D) contradicts it.

(D)

Topics:Adsorption