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← JEE Main 2022 · 29 Jul · Shift 1
ChemistrySingle correct+4 / -1Question 75 of 90

JEE Main 2022 · 29 Jul · Shift 1, Chemistry question 75

4-Hydroxybenzaldehyde is treated with Br2_2 to give A; A with NH2_2OH gives B; B is heated with P2_2O5_5 to give C.

Consider the above reaction sequence, the Product 'C' is :

Scheme: 4-hydroxybenzaldehyde → (Br2) A → (NH2OH) B → (P2O5, Δ) C.
Choose one option
Answer and worked solution

Official answer: D

Sequence. The OH directs bromination to both ortho positions: 3,5-dibromo-4-hydroxybenzaldehyde. NH₂OH gives the oxime, and P₂O₅ dehydrates it to the nitrile: 3,5-dibromo-4-hydroxybenzonitrile.

(D)