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← JEE Main 2022 · 26 Jul · Shift 2
ChemistryInteger+4 / -1Question 83 of 90

JEE Main 2022 · 26 Jul · Shift 2, Chemistry question 83

For the reaction

H2F2(g)→H2(g)+F2(g)\mathrm{H_2F_2(g)\rightarrow H_2(g)+F_2(g)}

ΔU=−59.6\Delta U=-59.6 kJ mol−1^{-1} at 27°C.

The enthalpy change for the above reaction is (−) ______ kJ mol−1^{-1} [nearest integer]

Given: R = 8.314 J K−1^{-1} mol−1^{-1}.

Answer and worked solution

Official answer: 57

ΔH=ΔU+ΔngRT\Delta H=\Delta U+\Delta n_gRT with Δng=1\Delta n_g=1: −59.6+8.314×3001000=−57.1-59.6+\frac{8.314\times300}{1000}=-57.1 kJ mol−1^{-1}.

Answer: 57