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← JEE Main 2022 · 28 Jun · Shift 2
ChemistrySingle correct+4 / -1Question 64 of 90

JEE Main 2022 · 28 Jun · Shift 2, Chemistry question 64

A student needs to prepare a buffer solution of propanoic acid and its sodium salt with pH 4. The ratio of [CH3CH2COO−][CH3CH2COOH]\dfrac{\left[\mathrm{CH_3CH_2COO^-}\right]}{\left[\mathrm{CH_3CH_2COOH}\right]} required to make buffer is ______.

Given : Ka(CH3CH2COOH)=1.3×10−5K_a\left(\mathrm{CH_3CH_2COOH}\right)=1.3\times10^{-5}

Choose one option
Answer and worked solution

Official answer: B

Henderson. [salt][acid]=Ka[H+]=1.3×10−510−4=0.13\dfrac{[\text{salt}]}{[\text{acid}]}=\dfrac{K_a}{[\mathrm H^+]}=\dfrac{1.3\times10^{-5}}{10^{-4}}=0.13.

(B)