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← JEE Main 2022 · 27 Jun · Shift 2
ChemistrySingle correct+4 / -1Question 63 of 90

JEE Main 2022 · 27 Jun · Shift 2, Chemistry question 63

Statement I: Leaching of gold with cyanide ion in absence of air / O2\mathrm{O_2} leads to cyano complex of Au(III).

Statement II: Zinc is oxidized during the displacement reaction carried out for gold extraction.

In the light of the above statements, choose the correct answer from the options given below.

Choose one option
Answer and worked solution

Official answer: D

Statement I is false: leaching needs air/O₂ and gives [Au(CN)2]−\mathrm{[Au(CN)_2]^-}, an Au(I) complex. Statement II is true: Zn is oxidised to [Zn(CN)4]2−\mathrm{[Zn(CN)_4]^{2-}}.

(D)