Skip to content
dronacharya.ai
← JEE Main 2022 · 26 Jun · Shift 1
ChemistrySingle correct+4 / -1Question 71 of 90

JEE Main 2022 · 26 Jun · Shift 1, Chemistry question 71

Consider the following reaction :
A+alkali→B (Major Product)\mathrm{A+alkali\rightarrow B\ (Major\ Product)}
If B is an oxoacid of phosphorus with no P-H bond, then A is :

Choose one option
Answer and worked solution

Official answer: B

Eliminate. White P4\mathrm{P_4} with alkali gives PH3\mathrm{PH_3} and hypophosphite, H2PO2−\mathrm{H_2PO_2^-} (two P-H bonds). P2O3\mathrm{P_2O_3} and H3PO3\mathrm{H_3PO_3} give phosphite, HPO32−\mathrm{HPO_3^{2-}} (one P-H bond).

Keyed answer. That leaves red phosphorus, which NTA's key gives; its product is taken as an oxoacid without a P-H bond.

(B)