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← JEE Main 2021 · 24 Feb · Shift 1
ChemistryInteger+4 / -1Question 57 of 90

JEE Main 2021 · 24 Feb · Shift 1, Chemistry question 57

The reaction of sulphur in alkaline medium is given below :

S8(s)+a OH(aq)−→b S(aq)2−+c S2O32−(aq)+d H2O(l)\mathrm{S_{8(s)}+a\,OH^-_{(aq)}\to b\,S^{2-}_{(aq)}+c\,S_2O_3^{2-}{}_{(aq)}+d\,H_2O_{(l)}}

The values of 'a' is _______. (Integer answer)

Answer and worked solution

Official answer: 12

Balanced S8+12OH−→4S2−+2S2O32−+6H2O\mathrm{S_8+12OH^-\to4S^{2-}+2S_2O_3^{2-}+6H_2O} (sulphur disproportionates to −2 and +2): a=12a=12.

Answer: 12