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← JEE Main 2015 · 10 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 49 of 90

JEE Main 2015 · 10 Apr · Shift 1, Chemistry question 49

The correct statement on the isomerism associated with the following complex ions,

(a) [Ni(HX2O)X5NHX3]X2+\ce{[Ni(H2O)5NH3]^2+}, (b) [Ni(HX2O)X4(NHX3)X2]X2+\ce{[Ni(H2O)4(NH3)2]^2+} and (c) [Ni(HX2O)X3(NHX3)X3]X2+\ce{[Ni(H2O)3(NH3)3]^2+} is :

Choose one option
Answer and worked solution

Official answer: D

  • (a) [MAX5B]\ce{[MA5B]}: no isomers.
  • (b) [MAX4BX2]\ce{[MA4B2]}: cis and trans.
  • (c) [MAX3BX3]\ce{[MA3B3]}: fac and mer.

None of these is chiral, so (b) and (c) show only geometrical isomerism.