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← JEE Main 2014 · 12 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 50 of 90

JEE Main 2014 · 12 Apr · Shift 1, Chemistry question 50

Which one of the following complexes will most likely absorb visible light ?

(At nos. Sc = 21, Ti = 22, V = 23, Zn = 30)

Choose one option
Answer and worked solution

Official answer: C

Colour needs partly filled d orbitals.

  • ScX3+\ce{Sc^3+}: d0d^0.
  • TiX4+\ce{Ti^4+}: d0d^0.
  • ZnX2+\ce{Zn^2+}: d10d^{10}.
  • VX3+\ce{V^3+}: d2d^2, so d-d transitions absorb visible light.