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← JEE Main 2014 · 11 Apr · Shift 1
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JEE Main 2014 · 11 Apr · Shift 1, Chemistry question 45

A gaseous compound of nitrogen and hydrogen contains 12.5% (by mass) of hydrogen. The density of the compound relative to hydrogen is 16. The molecular formula of the compound is :

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Answer and worked solution

Official answer: D

Mass ratio N : H is 87.5 : 12.5, i.e. moles 6.25:12.5=1:26.25:12.5=1:2, so the empirical formula is NHX2\ce{NH2} (16). The molar mass is 2×16=322\times16=32, giving NX2HX4\ce{N2H4}.