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← JEE Main 2014 · 9 Apr · Shift 1
ChemistrySingle correct+4 / -1Question 47 of 90

JEE Main 2014 · 9 Apr · Shift 1, Chemistry question 47

In the following sets of reactants which two sets best exhibit the amphoteric character of AlX2OX3 ⋅ x HX2O\ce{Al2O3.xH2O} ?

Set 1 : AlX2OX3 ⋅ x HX2O(s)\ce{Al2O3.xH2O(s)} and OHX−(aq)\ce{OH-(aq)}

Set 2 : AlX2OX3 ⋅ x HX2O(s)\ce{Al2O3.xH2O(s)} and HX2O(l)\ce{H2O(l)}

Set 3 : AlX2OX3 ⋅ x HX2O(s)\ce{Al2O3.xH2O(s)} and HX+(aq)\ce{H+(aq)}

Set 4 : AlX2OX3 ⋅ x HX2O(s)\ce{Al2O3.xH2O(s)} and NHX3(aq)\ce{NH3(aq)}

Choose one option
Answer and worked solution

Official answer: B

Amphoteric means it reacts with both bases and acids:

  • AlX2OX3 ⋅ x HX2O+OHX−\ce{Al2O3.xH2O + OH-} gives aluminate (set 1);
  • AlX2OX3 ⋅ x HX2O+HX+\ce{Al2O3.xH2O + H+} gives AlX3+\ce{Al^3+} (set 3).
Topics:Group 13