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← JEE Advanced 2024 · Paper 2
ChemistrySingle correct+3 / -1Question 36 of 51

JEE Advanced 2024 · Paper 2, Chemistry question 2

In a metal deficient oxide sample, MXY2O4\mathbf{M_XY_2O_4} (M and Y are metals), M is present in both +2 and +3 oxidation states and Y is in +3 oxidation state. If the fraction of M2+\mathbf{M^{2+}} ions present in M is 13\dfrac13, the value of X is _____.

Choose one option
Answer and worked solution

Official answer: D

Charge balance in MXXYX2OX4\ce{M_XY2O4}:

  • the oxide ions carry −8-8;
  • YX2\ce{Y2} carries +6+6;
  • so the XX atoms of M must carry +2+2 in total.

Average charge of M. One third is MX2+\ce{M^2+} and two thirds MX3+\ce{M^3+}:
13(2)+23(3)=83.\tfrac13(2)+\tfrac23(3)=\tfrac83.

X⋅83=2  ⟹  X=34=0.75.X\cdot\frac83=2\implies X=\frac34=0.75.