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← JEE Advanced 2017 · Paper 1
ChemistryInteger+3Question 28 of 54

JEE Advanced 2017 · Paper 1, Chemistry question 10

The sum of the number of lone pairs of electrons on each central atom in the following species is

[TeBrX6]X2−\ce{[TeBr6]^{2-}}, [BrFX2]X+\ce{[BrF2]+}, SNFX3\ce{SNF3}, and [XeFX3]X−\ce{[XeF3]-}

(Atomic numbers: N = 7, F = 9, S = 16, Br = 35, Te = 52, Xe = 54)

Answer and worked solution

Official answer: 6

Count the lone pairs left on each central atom:

Species Valence electrons Used in bonds Lone pairs
[TeBrX6]X2−\ce{[TeBr6]^{2-}} 6 + 2 = 8 6 1
[BrFX2]X+\ce{[BrF2]+} 7 − 1 = 6 2 2
SNFX3\ce{SNF3} (S≡N, 3 S-F) 6 6 0
[XeFX3]X−\ce{[XeF3]-} 8 + 1 = 9 3 3

Total: 1+2+0+3=61+2+0+3=6.

Answer: 6