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← IIT-JEE 2011 · Paper 1
ChemistryInteger+4Question 22 of 69

IIT-JEE 2011 · Paper 1, Chemistry question 22

The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is

Answer and worked solution

Official answer: 5

β-hydrogens of CHX3CHX2−C(Br)(CX5HX9)−CHX2CHX2CHX3\ce{CH3CH2-C(Br)(C5H9)-CH2CH2CH3} are on C2, C4 and the ring CH.

  • C2=C3: C3 carries a propyl and a cyclopentyl, C2 a methyl and H: E and Z (2).
  • C3=C4: C3 carries an ethyl and a cyclopentyl, C4 an ethyl and H: E and Z (2).
  • C3=ring carbon (cyclopentylidene): the ring is symmetric, one alkene (1).

Total 5.

Answer: 5