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← IIT-JEE 2010 · Paper 1
ChemistrySingle correct+3 / -1Question 15 of 84

IIT-JEE 2010 · Paper 1, Chemistry question 15

Passage

Paragraph for Questions 14 to 16

Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite (CuSOX4 ⋅ 5 HX2O\ce{CuSO4.5H2O}), atacamite (CuX2Cl(OH)X3\ce{Cu2Cl(OH)3}), cuprite (CuX2O\ce{Cu2O}), copper glance (CuX2S\ce{Cu2S}) and malachite (CuX2(OH)X2COX3\ce{Cu2(OH)2CO3}). However, 80% of the world copper production comes from the ore chalcopyrite (CuFeSX2\ce{CuFeS2}). The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.

Iron is removed from chalcopyrite as

Choose one option
Answer and worked solution

Official answer: D

Slag formation. In the smelting step silica is added as a flux; it combines with the basic FeO formed on roasting:
FeO+SiOX2→FeSiOX3.\ce{FeO + SiO2 -> FeSiO3}.
The ferrous silicate slag floats off the matte.

(D)