Skip to content
dronacharya.ai
← IIT-JEE 2007 · Paper 1
ChemistrySingle correct+4 / -1Question 40 of 66

IIT-JEE 2007 · Paper 1, Chemistry question 40

Passage

Paragraph for Question Nos. 39 to 41

Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately 6.023×10236.023\times10^{23}) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.

A 4.0 molar aqueous solution of NaCl is prepared and 500 mL of this solution is electrolysed. This leads to the evolution of chlorine gas at one of the electrodes (atomic mass: Na = 23, Hg = 200; 1 Faraday = 96500 coulombs).

If the cathode is a Hg electrode, the maximum weight (g) of amalgam formed from this solution is

Choose one option
Answer and worked solution

Official answer: D

With a mercury cathode sodium is discharged and forms the amalgam: NaX++eX−+Hg→Na−Hg\ce{Na+ + e- + Hg -> Na-Hg}. All 2.0 mol of Na can be deposited.

Mass of amalgam (taken as NaHg): 2×(23+200)=4462\times(23+200)=446 g.

(D)